Discovery, synthesis, and characterization of an isomeric coordination polymer with pillared kagome net topology

Citations

WEB OF SCIENCE

90
Citations

SCOPUS

99

초록

A topological isomer based on Zn-2 paddlewheel, dicarboxylate, and diamine ligands is synthesized by solvothermal methods after careful modulation of the reaction conditions. The new framework is characterized by a pillared Kagome net topology and possesses a sustainable pore structure with high surface area (similar to 2400 m(2)/g) and large hexagonal channels (similar to 15 angstrom).

키워드

METAL-ORGANIC FRAMEWORK; GAS SORPTION PROPERTIES; HIGH H-2 ADSORPTION; HYDROGEN STORAGE; ENANTIOSELECTIVE SORPTION; PERMANENT POROSITY; ROOM-TEMPERATURE; BUILDING-BLOCKS; POROUS MATERIAL; SQUARE
제목
Discovery, synthesis, and characterization of an isomeric coordination polymer with pillared kagome net topology
저자
Chun, Hyungphil; Moon, Jumi
DOI
10.1021/ic070036t
발행일
2007-05
유형
Article
저널명
Inorganic Chemistry
권
46
호
11
페이지
4371 ~ 4373