Unique Coordination-Based Heterometallic Approach for the Stoichiometric Inclusion of High-Valent Metal Ions in a Porous Metal-Organic Framework

Hong, Keunil; Bak, Woojeong; Chun, Hyungphil

doi:10.1021/ic400607w

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Unique Coordination-Based Heterometallic Approach for the Stoichiometric Inclusion of High-Valent Metal Ions in a Porous Metal-Organic Framework

Hong, Keunil;
Bak, Woojeong;
Chun, Hyungphil

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WEB OF SCIENCE

42

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SCOPUS

43

초록

A heterometallic metal-organic framework incorporating Zn2+ and Ti4+ is successfully synthesized. The unique coordination mode of each metal ion to 2-oxido-1,4-benzenedicarboxylate leads to Zn6Ti2 building blocks, which extend to form a double-walled primitive cubic net. This material possesses a permanent porosity and long-term stability.

키워드

CARBOXYLATE; STABILITY; CO2; SITES; FLUE-GAS; SEPARATION; ADSORPTION; CARBON-DIOXIDE; CAPTURE; CATALYSTS; CARBON-DIOXIDE; FLUE-GAS; CAPTURE; CO; 2ADSORPTION; SEPARATION; CARBOXYLATE; STABILITY; CAPACITY; LIGAND

제목: Unique Coordination-Based Heterometallic Approach for the Stoichiometric Inclusion of High-Valent Metal Ions in a Porous Metal-Organic Framework

저자: Hong, Keunil; Bak, Woojeong; Chun, Hyungphil

DOI: 10.1021/ic400607w

발행일: 2013-05

유형: Article

저널명: Inorganic Chemistry

권: 52

호: 10

페이지: 5645 ~ 5647

언어: ENG

출판사: AMER CHEMICAL SOC

발행국가: 미국

분량: 3 페이지

ISSN: P 0020-1669