A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity

  • Dybtsev, Danil N.; 
  • Nuzhdin, Alexey L.; 
  • Chun, Hyungphil; 
  • Bryliakov, Konstantin P.; 
  • Talsi, Evgeniy P.; 
  • 외 2명
Citations

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615
Citations

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651

초록

A handy approach: A new synthetic approach starting from readily available chemicals successfully produces a robust homochiral metal-organic microporous framework. The material exhibits size- and enantioselective guest-sorption properties (see picture), as well as remarkable catalytic activity with size- and chemoselectivity, and high conversion in the oxidation of thioethers to sulfoxides. (Figure Presented).

키워드

chirality; heterogeneous catalysis; metal-organic frameworks; microporous materials; sorption; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; SULFIDE OXIDATION; HYDROGEN STORAGE; POROUS MATERIAL; GIANT PORES; 1ST EXAMPLE; FRAMEWORK; DESIGN; ADSORPTION
제목
A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity
저자
Dybtsev, Danil N.; Nuzhdin, Alexey L.; Chun, Hyungphil; Bryliakov, Konstantin P.; Talsi, Evgeniy P.; Fedin, Vladimir P.; Kim, Kimoon
DOI
10.1002/anie.200503023
발행일
2006-01
유형
Article
저널명
Angewandte Chemie International Edition
권
45
호
6
페이지
916 ~ 920