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A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity
- Dybtsev, Danil N.;
- Nuzhdin, Alexey L.;
- Chun, Hyungphil;
- Bryliakov, Konstantin P.;
- Talsi, Evgeniy P.;
- 외 2명
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615Citations
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651초록
A handy approach: A new synthetic approach starting from readily available chemicals successfully produces a robust homochiral metal-organic microporous framework. The material exhibits size- and enantioselective guest-sorption properties (see picture), as well as remarkable catalytic activity with size- and chemoselectivity, and high conversion in the oxidation of thioethers to sulfoxides. (Figure Presented).
키워드
chirality; heterogeneous catalysis; metal-organic frameworks; microporous materials; sorption; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; SULFIDE OXIDATION; HYDROGEN STORAGE; POROUS MATERIAL; GIANT PORES; 1ST EXAMPLE; FRAMEWORK; DESIGN; ADSORPTION
- 제목
- A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity
- 저자
- Dybtsev, Danil N.; Nuzhdin, Alexey L.; Chun, Hyungphil; Bryliakov, Konstantin P.; Talsi, Evgeniy P.; Fedin, Vladimir P.; Kim, Kimoon
- 발행일
- 2006-01
- 유형
- Article
- 권
- 45
- 호
- 6
- 페이지
- 916 ~ 920
- 언어
- ENG
- 출판사
- WILEY-V C H VERLAG GMBH
- 발행국가
- 독일
- 분량
- 5 페이지
- ISSN
- E 1521-3773
P 1433-7851