Chemical synthesis of Nd2Fe14B/Fe-Co nanocomposite with high magnetic energy product

초록

Nd2Fe14B is one of the most popular permanent magnets (PMs) possessing the best energy product (BH)(max) among the common PM materials. However, exchange-coupled nanocomposite magnets fabricated by embedding nanostructures of soft-phase magnetic materials into a hard-phase magnetic matrix manifest higher remanence and a higher energy product. Here we present the fabrication of exchange coupled Nd2Fe14B/Fe-Co magnetic nanocomposites using gel-combustion and diffusion-reduction processes. Pre-fabricated CoFe2O4 nanoparticles (NPs) of similar to 5 nm diameter were incorporated into a Nd-Fe-B oxide matrix during its synthesis by gel-combustion. The obtained mixed oxide was further processed with oxidative annealing at 800 degrees C for 2 h and reductive annealing at 900 degrees C for 2 h to form a Nd2Fe14B/Fe-Co nanocomposite. Nanocomposites with different mol% of soft-phase were prepared and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and physical property measurement system (PPMS) to study their crystalline phase, morphology and magnetic behavior. Addition of 7.7 mol% of soft-phase was found to be optimum, producing a coercivity (H-c) of 5.6 kOe and remanence (M-r) of 54 emu g(-1) in the nanocomposite.

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