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Palladium-Catalyzed Carbonylative Coupling Reactions of N,N-Bis(methanesulfonyl)amides through C-N Bond Cleavage
- Lim, Minkyung;
- Kim, Hyeji;
- Ban, Jaeyoung;
- Son, Junghan;
- Lee, Jae Kyun;
- ... Min, Sun-Joon;
- 외 2명
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16초록
Palladium-catalyzed carbonylative coupling reactions of various N,N-bis(methanesulfonyl)amides with arylboronic acids through C-N bond cleavage were carried out. The reactions proceeded under mild conditions in a short period of time without any additives to afford a wide range of unsymmetrical aryl ketones in excellent yields. This is the first example of a carbonylative coupling reaction using N,N-bis(methanesulfonyl)amide as a coupling substrate.
키워드
Synthetic methods; Palladium; C-N bond cleavage; Amides; Cross-coupling; FRIEDEL-CRAFTS ACYLATION; ELECTRONICALLY-ACTIVATED AMIDES; ACYL-TRANSFER REAGENTS; SUZUKI-MIYAURA; ARYLBORONIC ACIDS; CARBOXYLIC ANHYDRIDES; KETONE SYNTHESIS; DIARYL KETONES; IONIC LIQUIDS; ARYL BROMIDES
- 제목
- Palladium-Catalyzed Carbonylative Coupling Reactions of N,N-Bis(methanesulfonyl)amides through C-N Bond Cleavage
- 저자
- Lim, Minkyung; Kim, Hyeji; Ban, Jaeyoung; Son, Junghan; Lee, Jae Kyun; Min, Sun-Joon; Lee, Sang Uck; Rhee, Hakjune
- 발행일
- 2018-11
- 유형
- Article
- 권
- 2018
- 호
- 41
- 페이지
- 5717 ~ 5724
- 언어
- ENG
- 출판사
- WILEY-V C H VERLAG GMBH
- 발행국가
- 독일
- 분량
- 8 페이지
- ISSN
- E 1099-0690
P 1434-193X