Hierarchical Super-Hydrophilic Aluminum Oxide Architectures on Textured Silicon for Aqueous- and Vapor-Phase Interaction

초록

Hierarchical super-hydrophilic surfaces were realized by forming porous anodic aluminum oxide (AAO) and boehmite [AlO(OH)] on micro-textured Si wafers. One-step anodization of e-beam-deposited Al followed by controlled pore-widening, thermal annealing, or hot-water treatment produced oxide architectures exhibiting near-zero water contact angles (aqueous regime) and pronounced H2O adsorption-desorption responses (vapor regime). Thermogravimetric analysis, moisture isotherms, and FT-IR indicate that increased porosity and anion incorporation (O-/O2-/oxalate) enrich surface hydroxyl functionality, enhancing affinity to H2O. The results delineate two complementary regimes-rapid capillary wetting and multilayer vapor adsorption-supporting the use of these oxide/Si hierarchies as interactive water-affine interfaces with potential relevance to moisture gettering and chemosensing.

키워드