Unprecedented and highly symmetric (6,8)-connected topology in a porous metal-organic framework through a Zn-Ti heterometallic approach

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33

초록

The Zn(II)-Ti(IV) heterometallic approach is successfully adopted to produce a highly symmetric, binodal metal-organic framework with unprecedented topology in network solids. This material, ZTOF-2, possesses permanent porosity as shown by reversible sorption of various gases.

키워드

METALLOLIGAND; NETS; CARBON-DIOXIDE CAPTURE; CRYSTAL-STRUCTURE; BEHAVIOR; SITES; SEPARATION; MOFS; CATALYSTS; CARBON-DIOXIDE; CAPTURECRYSTAL-STRUCTURE; SEPARATION; METALLOLIGAND; BEHAVIOR; SITES
제목
Unprecedented and highly symmetric (6,8)-connected topology in a porous metal-organic framework through a Zn-Ti heterometallic approach
저자
Hong, Keunil; Chun, Hyungphil
DOI
10.1039/c3cc46761a
발행일
2013-10
유형
Article
저널명
Chemical Communications
권
49
호
93
페이지
10953 ~ 10955