Effects of Catalyst Promotion on the Selective Hydrogenation of Biphenol Using Various Pd/C Catalysts

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초록

The effect of sodium (Na) promotion was studied in the biphenol (BP) hydrogenation using various Pd/C catalysts. Different amounts of sodium metal were used for promotion with Pd/C and their effects on BP hydrogenation were observed. The promotion order was changed to compare the effect of the position of the promoter in relation to the palladium (Pd) metal on the catalytic activity and yield of the final product, bicyclohexyl-4,4'-diol (BHD). Pd/C catalysts prepared from different methods were also sodium-promoted and the changes of the reaction pathway according to the type of promoted Pd/C catalyst were compared.

키워드

Sodium promotion; Pre-impregnation; Co-impregnation; Post-impregnation; Biphenol hydrogenation; PALLADIUM ALUMINA CATALYSTS; PHENOL; CYCLOHEXANONE; RUTHENIUM; PLATINUM
제목
Effects of Catalyst Promotion on the Selective Hydrogenation of Biphenol Using Various Pd/C Catalysts
저자
Cho, Hong-Baek; Hong, Bum-Eui; Park, Jai-Hyun; Ahn, Sung-Hyun; Park, Yeung-Ho
DOI
10.5012/bkcs.2008.29.12.2434
발행일
2008-12
유형
Article
저널명
Bulletin of the Korean Chemical Society
권
29
호
12
페이지
2434 ~ 2440