Surface interaction and inhibition mechanisms of hydrazide derivatives on N80 steel in acidizing media: A comprehensive analysis through experimental and theoretical methods

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초록

This study evaluates hydrazide derivatives, PEH and PAH, as corrosion inhibitors for N80 steel in acidic conditions. Utilizing a blend of experimental tests and theoretical calculations, including EIS, PDP, SEM, DFTB, and MD simulations, up to 96% inhibition efficiency was attained. Specifically, the PAH compound displayed notable protection. The Langmuir adsorption model confirmed dual adsorption, and theoretical simulations revealed interaction mechanisms. The research provides valuable insights into the formation of covalent bonds between inhibitor molecules and iron atoms, and offers a promising path for the development of advanced corrosion inhibitors suitable for industrial applications.

키워드

Corrosion inhibition; Hydrazide; N80 steel; Density functional theory; Molecular dynamics; GREEN CORROSION-INHIBITOR; MILD-STEEL; WEIGHT-LOSS; DFT; ADSORPTION; INSIGHTS; QUANTUM
제목
Surface interaction and inhibition mechanisms of hydrazide derivatives on N80 steel in acidizing media: A comprehensive analysis through experimental and theoretical methods
저자
El-Haitout, Badr; Lgaz, Hassane; Al-Hadeethi, Mustafa R.; Lee, Han-Seung; Adnin, Raihana Jannat; Messali, Mouslim; Haboubi, Khadija; Bazzi, Lahcen; Salghi, Rachid
DOI
10.1016/j.cplett.2023.140980
발행일
2024-01
유형
Article
저널명
Chemical Physics Letters
권
834
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1 ~ 21