Long-term durable silicon photocathode protected by a thin Al2O3/SiOx layer for photoelectrochemical hydrogen evolution

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초록

The long-term steady production of H-2 is vital for p-Si photocathodes. However, the oxidation of a Si photoelectrode substantially deteriorates its performance, over time. This study demonstrates that a thin Al2O3 layer deposited over the Si can prevent oxidation and also reduce overpotential, via a surface passivation effect.

키워드

WATER REDUCTION; ENERGY; SOLAR-CELLS; SURFACE PASSIVATION; DEPOSITION; ARRAY PHOTOCATHODES; PHOTOANODES; H-2 EVOLUTION; CATALYSTS; TIO2; SURFACE PASSIVATION; SOLAR-CELLS; DEPOSITION; ENERGY; TIO2; NANOWIRES; CATALYSTS; NI
제목
Long-term durable silicon photocathode protected by a thin Al2O3/SiOx layer for photoelectrochemical hydrogen evolution
저자
Choi, Mi Jin; Jung, Jin-Young; Park, Min-Joon; Song, Jae-Won; Lee, Jung-Ho; Bang, Jin Ho
DOI
10.1039/c3ta14443g
발행일
2013-12
유형
Article
저널명
Journal of Materials Chemistry A
권
2
호
9
페이지
2928 ~ 2933