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Metal-free Synthesis of beta-Nitrostyrenes via DDQ-Catalyzed Nitration
- Park, Sangwoon;
- Yoon, Seungri;
- Min, Sun-Joon
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6초록
In this study, we have developed a facile synthesis of (E)-β-nitrostyrenes by using tert-butyl nitrite as a source of nitro group and DDQ as a key oxidant under aerobic condition. This process highlighted that a wide range of β-nitrostyrenes could be synthesized under mild metal-free reaction conditions at room temperature starting from readily available styrenes.
키워드
STEREOSELECTIVE NITRATION; SELECTIVE NITRATION; OLEFINS; NITROALKENES; DERIVATIVES; OXIDATION; EFFICIENT; STYRENES; REAGENT; ACCESS
- 제목
- Metal-free Synthesis of beta-Nitrostyrenes via DDQ-Catalyzed Nitration
- 저자
- Park, Sangwoon; Yoon, Seungri; Min, Sun-Joon
- 발행일
- 2021-03
- 유형
- Article
- 권
- 42
- 호
- 3
- 페이지
- 525 ~ 528