High-Performance Randomly Oriented Zeolite Membranes Using Brittle Seeds and Rapid Thermal Processing

  • Yoo, Won Cheol; 
  • Stoeger, Jared A.; 
  • Lee, Pyung-Soo; 
  • Tsapatsis, Michael; 
  • Stein, Andreas
Citations

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57
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63

초록

MFI zeolite membranes with high flux and high separation factors for xylene isomer separation were fabricated by combining several unique processing steps. These include 1) use of brittle seeds prepared by confined synthesis, 2) rubbing and leveling methods to obtain randomly oriented seed layers, 3) secondary hydrothermal growth to produce thin zeolite films, and 4) rapid thermal processing to remove structure-directing agents while minimizing crack formation (see picture; scale bar 500 nm).

키워드

hydrothermal synthesis; separation; thin films; zeolite membranes; zeolites; CONFINED SPACE SYNTHESIS; SECONDARY GROWTH; MFI MEMBRANES; FILMS; SEPARATION; CRYSTALLIZATION; MICROSTRUCTURE; FABRICATION; PERMEATION; MONOLAYERS
제목
High-Performance Randomly Oriented Zeolite Membranes Using Brittle Seeds and Rapid Thermal Processing
저자
Yoo, Won Cheol; Stoeger, Jared A.; Lee, Pyung-Soo; Tsapatsis, Michael; Stein, Andreas
DOI
10.1002/anie.201004029
발행일
2010-09
유형
Article
저널명
Angewandte Chemie International Edition
권
49
호
46
페이지
8699 ~ 8703