Palladium Nanoparticles on Thermoresponsive Hydrogels and their Application as Recyclable Suzuki-Miyaura Coupling Reaction Catalysts in Water

  • Hong, Myeng Chan; 
  • Choi, Myung Chan; 
  • Chang, Young Wook; 
  • Lee, Yongwoo; 
  • Kim, Jongsik; 
  • 외 1명
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초록

Palladium nanoparticles were immobilized on PNIPAM:4-VP hydrogels. The resultant pualladium catalysts showed high activities for SuzukiMiyaura coupling reactions in water. The recyclability of the catalysts was improved by using 4-VP as a co-monomer in the hydrogels due to reduced Pd leaching during the reactions.

키워드

palladium nanoparticles; PNIPAM:4-VP co-polymers; reusable catalysts; Suzuki-Miyaura reactions; water; SUPPORTED PD CATALYSTS; ARYL HALIDES; HETEROGENEOUS SUZUKI; ARYLBORONIC ACIDS; REUSABLE CATALYST; ACTIVE CATALYSTS; PHASE-TRANSITION; ROOM-TEMPERATURE; IONIC LIQUIDS; EFFICIENT
제목
Palladium Nanoparticles on Thermoresponsive Hydrogels and their Application as Recyclable Suzuki-Miyaura Coupling Reaction Catalysts in Water
저자
Hong, Myeng Chan; Choi, Myung Chan; Chang, Young Wook; Lee, Yongwoo; Kim, Jongsik; Rhee, Hakjune
DOI
10.1002/adsc.201100965
발행일
2012-05
유형
Article
저널명
Advanced Synthesis & Catalysis
권
354
호
7
페이지
1257 ~ 1263