(E)-2,2 '-[3-(2-Nitrophenyl)prop-2-ene-1,1-diyl]bis(3-hydroxy-5,5-dimethylcycloh ex-2-en-1-one)

Citations

WEB OF SCIENCE

7
Citations

SCOPUS

5

초록

In the title compound, C25H29NO6, each of the cyclohexenone rings adopts a half-chair conformation. Each of the pairs of hydroxy and carbonyl O atoms are oriented to allow for the formation of intramolecular O-H center dot center dot center dot O hydrogen bonds, which are typical of xanthene derivatives. The nitro group is rotationally disordered over two orientations in a 0.544 (6):0.456 (6) ratio. In the crystal, weak intermolecualr C-H center dot center dot center dot O hydrogen bonds link molecules into layers parallel to the ab plane.

키워드

data-to-parameter ratio = 13.4; disorder in main residue; mean σ(C-C) = 0.007 Å; R factor = 0.064; single-crystal X-ray study; T = 298 K; wR factor = 0.191
제목
(E)-2,2 '-[3-(2-Nitrophenyl)prop-2-ene-1,1-diyl]bis(3-hydroxy-5,5-dimethylcycloh ex-2-en-1-one)
저자
Cha, Joo Hwan; Kim, Young Hee; Min, Sun-Joon; Cho, Yong Seo; Lee, Jae Kyun
DOI
10.1107/S1600536811043686
발행일
2011-12
유형
Article
저널명
Acta Crystallographica Section E: Structure Reports Online
권
67
페이지
O3153 ~ U908