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(E)-2,2 '-[3-(2-Nitrophenyl)prop-2-ene-1,1-diyl]bis(3-hydroxy-5,5-dimethylcycloh ex-2-en-1-one)
- Cha, Joo Hwan;
- Kim, Young Hee;
- Min, Sun-Joon;
- Cho, Yong Seo;
- Lee, Jae Kyun
Citations
WEB OF SCIENCE
7Citations
SCOPUS
5초록
In the title compound, C25H29NO6, each of the cyclohexenone rings adopts a half-chair conformation. Each of the pairs of hydroxy and carbonyl O atoms are oriented to allow for the formation of intramolecular O-H center dot center dot center dot O hydrogen bonds, which are typical of xanthene derivatives. The nitro group is rotationally disordered over two orientations in a 0.544 (6):0.456 (6) ratio. In the crystal, weak intermolecualr C-H center dot center dot center dot O hydrogen bonds link molecules into layers parallel to the ab plane.
키워드
data-to-parameter ratio = 13.4; disorder in main residue; mean σ(C-C) = 0.007 Å; R factor = 0.064; single-crystal X-ray study; T = 298 K; wR factor = 0.191
- 제목
- (E)-2,2 '-[3-(2-Nitrophenyl)prop-2-ene-1,1-diyl]bis(3-hydroxy-5,5-dimethylcycloh ex-2-en-1-one)
- 저자
- Cha, Joo Hwan; Kim, Young Hee; Min, Sun-Joon; Cho, Yong Seo; Lee, Jae Kyun
- 발행일
- 2011-12
- 유형
- Article
- 권
- 67
- 페이지
- O3153 ~ U908
- 언어
- ENG
- 출판사
- WILEY-BLACKWELL
- 발행국가
- 미국
- ISSN
- P 1600-5368